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ASTM D3239-91(2016)
Standard Test Method for Aromatic Types Analysis of Gas-Oil Aromatic Fractions by High Ionizing Voltage Mass Spectrometry (Withdrawn 2023)
15 стр.
Отменен
Электронный (pdf)Печатное издание
118.56 $ (включая НДС 20%)
Разработчик:
Зарубежные/ASTM
ICS:
75.080 Petroleum products in general / Нефтяные продукты в целом
Сборник (ASTM):
05.01 Petroleum Products, Liquid Fuels, and Lubricants (I): C1234–D3709 / Нефтепродукты, жидкое топливо и смазочные материалы (I): C1234–D3709
Тематика:
Petroleum
Описание
Причина отменыThis test method covered the determination by high ionizing voltage, low resolution mass spectrometry of 18 aromatic hydrocarbon types and 3 aromatic thiophenotypes in straight run aromatic petroleum fractions boiling within the range from 205 °C to 540 °C (400 °F to 1000 °F) (corrected to atmospheric pressure).

Formerly under the jurisdiction of Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants, this test method was withdrawn without replacement in March 2023. This test method was created in 1973 and had a precision statement but no referenced research report. ASTM archives do not have a research report on file; Form and Style Guide requires a research report. The test method was originally developed for specific types of magnetic sector mass spectrometers and published calculations were based on such instrumentation. As a result, there was no easy mechanism to update the test method without method development. In addition, the committee understands that this method may not be performed by many, if any, laboratories. ASTM will continue to provide copies of the test method for those that may need it. Committee D02.04M encourages members to submit potential replacement test method(s) based on newer technologies (e.g. MS-FIMS etc) that can be developed into ASTM approved test method(s).

Значение и использование

5.1 A knowledge of the hydrocarbon composition of process streams and petroleum products boiling within the range 205 °C to 540 °C (400 °F to 1000 °F) is useful in following the effect of changes in process variables, diagnosing the source of plant upsets, and in evaluating the effect of changes in composition on product performance properties. This method, when used together with Test Method D2786, provides a detailed analysis of the hydrocarbon composition of such materials.

Область применения

1.1 This test method2 covers the determination by high ionizing voltage, low resolution mass spectrometry of 18 aromatic hydrocarbon types and 3 aromatic thiophenotypes in straight run aromatic petroleum fractions boiling within the range from 205 °C to 540 °C (400 °F to 1000 °F) (corrected to atmospheric pressure). Samples must be nonolefinic, must contain not more than 1 % by mass of total sulfur, and must contain not more than 5 % nonaromatic hydrocarbons. Composition data are in volume percent.

Note 1: Although names are given to 15 of the compound types determined, the presence of other compound types of the same empirical formulae is not excluded. All other compound types in the sample, unidentified by name or empirical formula, are lumped into six groups in accordance with their respective homologous series.

1.2 The values stated in acceptable SI units are to be regarded as the standard. The values given in parentheses are provided for information purposes only.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Ключевые слова:
aromatic; gas oil; mass spectrometry; petroleum;