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ASTM E840-95(2000)
Standard Practice for Using Flame Photometric Detectors in Gas Chromatography
12 стр.
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Разработчик:
Зарубежные/ASTM
ICS:
71.040.50 Physicochemical. Including spectrophotometric and chromatographic analysis / Физико-химические методы анализа. Включая спектрофотометрический и хроматографический анализы17.180.30 Optical. Including spectroscopes, geodetic instruments, etc. / Оптические измерительные приборы. Включая спектроскопы, геодезические инструменты и т.д.
Сборник (ASTM):
03.06 Molecular Spectroscopy and Separation Science; Surface Analysis / Молекулярная спектроскопия; Анализ поверхности
Тематика:
Spectroscopy
Описание
Область применения

1.1 This practice is intended as a guide for the use of a flame photometric detector (FPD) as the detection component of a gas chromatographic system.

1.2 This practice is directly applicable to an FPD that employs a hydrogen-air flame burner, an optical filter for selective spectral viewing of light emitted by the flame, and a photomultiplier tube for measuring the intensity of light emitted.

1.3 This practice describes the most frequent use of the FPD which is as an element-specific detector for compounds containing sulfur (S) or phosphorus (P) atoms. However, nomenclature described in this practice are also applicable to uses of the FPD other than sulfur or phosphorus specific detection.

1.4 This practice is intended to describe the operation and performance of the FPD itself independently of the chromatographic column. However, the performance of the detector is described in terms which the analyst can use to predict overall system performance when the detector is coupled to the column and other chromatographic system components.

1.5 For general gas chromatographic procedures, Practice E260 should be followed except where specific changes are recommended herein for use of an FPD.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific safety information, see Section 4, Hazards.

Ключевые слова:
flame ionization detector (FID); flame photometric detectors (FPD); gas chromatography (GC); packed columns; supercritical fluid chromatography (SFC)