1.1 This test method covers the determination of the aromatic hydrogen content (Procedures A and B) and aromatic carbon content (Procedure C) of hydrocarbon oils using high-resolution nuclear magnetic resonance (NMR) spectrometers. Applicable samples include kerosenes, gas oils, mineral oils, lubricating oils, coal liquids, and other distillates that are completely soluble in chloroform at ambient temperature. For pulse Fourier transform (FT) spectrometers, the detection limit is typically 0.1 mol % aromatic hydrogen atoms and 0.5 mol % aromatic carbon atoms. For continuous wave (CW) spectrometers, which are suitable for measuring aromatic hydrogen contents only, the detection limit is considerably higher and typically 0.5 mol % aromatic hydrogen atoms.

1.2 The reported units are mole percent aromatic hydrogen atoms and mole percent aromatic carbon atoms.

1.3 This test method is not applicable to samples containing more than 1 mass % olefinic or phenolic compounds.

1.4 This test method does not cover the determination of the percentage mass of aromatic compounds in oils since NMR signals from both saturated hydrocarbons and aliphatic substituents on aromatic ring compounds appear in the same chemical shift region. For the determination of mass or volume percent aromatics in hydrocarbon oils, chromatographic, or mass spectrometry methods can be used.

1.5 The values stated in SI units are to be regarded as the standard.

This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 7.2 and 7.4.