Значение и использование

These test methods can be used to ensure that the chemical composition of the glass meets the compositional specification required for the finished glass product.

These test methods do not preclude the use of other methods that yield results within permissible variations. In any case, the analyst should verify the procedure and technique employed by means of a National Institute of Standards and Technology (NIST) standard reference material having a component comparable with that of the material under test. A list of standard reference materials is given in the NIST Special Publication 260, current edition.

Typical examples of products manufactured using soda-lime silicate glass are containers, tableware, and flat glass.

Typical examples of products manufactured using borosilicate glass are bakeware, labware, and fiberglass.

Typical examples of products manufactured using fluoride opal glass are containers, tableware, and decorative glassware.

Область применения

1.1 These test methods cover the quantitative chemical analysis of soda-lime and borosilicate glass compositions for both referee and routine analysis. This would be for the usual constituents present in glasses of the following types: (1) soda-lime silicate glass, (2) soda-lime fluoride opal glass, and (3) borosilicate glass. The following common oxides, when present in concentrations greater than indicated, are known to interfere with some of the determinations in this method: 2 % barium oxide (BaO), 0.2 % phosphorous pentoxide (P₂O₅), 0.05 % zinc oxide (ZnO), 0.05 % antimony oxide (Sb₂O₃), 0.05 % lead oxide (PbO).

1.2 The analytical procedures, divided into two general groups, those for referee analysis, and those for routine analysis, appear in the following order:

Sections Procedures for Referee Analysis: Silica10 BaO, R₂O₂ (Al₂O₃ + P₂O₅), CaO, and MgO11-15 Fe₂O₃, TiO ₂, ZrO₂ by Photometry and Al₂O₃ by Complexio-
metric Titration16-22 Cr₂O₃ by Volumetric and Photometric Methods23-25 MnO by the Periodate Oxidation Method26-29 Na₂O by the Zinc Uranyl Acetate Method and K₂O by the Tetraphenylborate Method 30-33 SO₃ (Total Sulfur)34 to 35 As₂O₃ by Volumetric Method36-40 Procedures for Routine Analysis: Silica by the Single Dehydration Method42-44 Al₂O₃, CaO, and MgO by Complexiometric Titration, and BaO, Na₂O, and K₂O by Gravimetric Method45-51 BaO, Al₂O₃, CaO, and MgO by Atomic Absorption; and Na₂O and K ₂O by Flame Emission Spectroscopy52-59 SO₃ (Total Sulfur)60 B₂O₃61 to 62 Fluorine by Pyrohydrolysis Separation and Specific Ion Electrode Measurement63-66 P₂O₅ by the Molybdo-Vanadate Method67-70 Colorimetric Determination of Ferrous Iron Using 1,10 Phenan throline71-76

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.