5.1 This test method provides an accurate and reliable procedure to measure the total heating value of a fuel gas, on a continuous basis, which is used for regulatory compliance, custody transfer, and process control.
5.2 Some instruments which conform to the requirements set forth in this test method can have response times on the order of 1 min or less and can be used for on-line measurement and control.
5.3 The method is sensitive to the presence of oxygen and nonparaffin fuels. For components not listed and composition ranges that fall outside those in Table 1 and Table 2, modifications in the method and changes to the calibration gas or gasses being used may be required to obtain correct results.
Область применения1.1 This test method covers the determination of the heating value of natural gases and similar gaseous mixtures within the range of composition shown in Table 1, and Table 2 that covers flare components but is not intended to limit the components to be measured in flare gases.
TABLE 1 Natural Gas Components and Range of Composition CoveredCompound
Concentration Range, mole, %
Helium
0.01 to 5
Nitrogen
0.01 to 20
Carbon dioxide
0.01 to 10
Methane
50 to 100
Ethane
0.01 to 20
Propane
0.01 to 20
n-butane
0.01 to 10
isobutane
0.01 to 10
n-pentane
0.01 to 2
Isopentane
0.01 to 2
Hexanes and heavier
0.01 to 2
Compound
CAS Number
Volatile Analytes
Acetone
67-64-1
Acetonitrile
75-05-8
Acrolein
107-05-8
Acrylonitrile
107-13-1
Benzene
71-43-2 2
1,3-Butadiene
106-99-0
Carbon disulfide
75-15-0
Chlorobenzene
108-90-7
Cumene (isopropylbenzene)
98-82-8
1,2-Dibromoethane
106-93-4
Ethylbenzene
100-41-4 2,2,4
Hexane
110-54-3
Methanol
67-56-1
Methyl isobutyl ketone
108-10-1
Methyl t-butyl ether
1634-04-4
Methylene chloride
75-09-2
Nitrobenzene
98-95-3
Nitropropane
79-46-9
Pentane2
109-66-0
Styrene
100-42-5
Tetrachloroethene
127-18-4
Toluene
108-88-3
Trichloroethene
79-01-6
Trimethylpentane
2 540-84-1
Xylenes (mixed isomers)
1330-20-7
Trimethylpentane
2 540-84-1
Xylenes (mixed isomers)
1330-20-7
Semi-volatile Analytes
Acenaphthene
83-32-9
Acenaphthylene
208-96-8
Aniline
62-53-3
Anthracene
120-12-7
Benzidine1
92-87-5
Benz[a]anthracene
56-55-3
Benzo[b]fluoranthene
205-99-2
Benzo[k]fluoranthene
207-08-9
Benzo[g,h,i]perylene
191-24-2
Benzo[a]pyrene
50-32-8
Benzo[e]pyrene2
192-97-2
Biphenyl2,
92-52-4
Cresol (mixed isomers)
1319-77-3
Chrysene
218-01-9
Dibenz[a,h]anthracene
53-70-3
Dibenzofuran
132-64-9
Dibenzo(a,e)pyrene
192-65-4
3,3’- Dimethoxybenzidine
119-90-4
Dimethylaminobenzene
60-11-7
7,12-Dimethylbenz(a)anthracene
57-97-6
3,3’- Dimethylbenzidine
119-93-7
á,á- Dimethylphenethylamine
122-09-8
2,4-Dimethylphenol
105-67-9
Fluoranthene
206-44-0
Fluorene
86-73-7
Indeno(1,2,3-cd)pyrene
193-39-5
Isophorone
78-59-1
3-Methylcholanthrene
56-49-5
2-Methylnaphthalene
91-57-6
Naphthalene
91-20-3
Perylene2
198-55-0
Phenanthrene
85-01-8
Phenol
108-95-2
1,4-Phenylenediamine
106-50-3
Pyrene
129-00-0
o-Toluidine
95-53-4
Aldehydes
Methanol
67-56-1
Formaldehyde
50-00-0
Acetaldehyde
75-07-0
Propanal
123-38-6
C1 to C5 Hydrocarbons
Description
Compound
CAS Number
C1 Alkanes
Methane
74-82-8
C2 Alkanes
Ethane
74-84-0
C3 Alkanes
Propane
74-98-6
C4 Alkanes
n-Butane
106-97-8
Isobutane
75-28-5
C5 Alkanes
n-Pentane
109-66-0
2-Methylbutane
78-78-4
Cyclopentane
287-92-3
C2 Olefins
Ethylene
74-85-1
C2 Alkanes
Acetylene
74-86-2
C3 Olefins
Propylene
115-07-1
C4 Olefins
1-Butene
106-98-9
2-Butene
107-01-7
Isobutene
115-11-7
C5 Olefins
1-Pentene
109-67-1
Cis-2-pentene
627-20-3
Trans-2-pentene
646-04-8
2-Methyl-1-butene
563-46-2
3-Methyl-1-butene
563-45-1
2-Methyl-2-butene
513-35-9
Cylcopentene
142-29-0
C3 Alkadienes
Propadiene
463-49-0
C4 Alkadienes
1,2-Butadiene
590-19-2
1,3-Butadiene
106-99-0
C5 Alkadienes
1,2-Pentadiene
591-95-7
1-cis-3-Pentadiene
1574-41-0
1-trans-3- Pentadiene
2004-70-8
1,4-Pentadiene
591-93-5
2,3-Pentadiene
591-96-8
3-Methyl-1,2- butadiene
598-25-4
2-Methyl-1,3- butadiene
78-79-5
Cyclopentadiene
542-92-7
Heating Value Range
Unit
Lower
Upper
Btu/ft3
83
2350
A Flare Gas Heating Value range defined in Table 2 is derived from the Evaluation of the Efficiency of Industrial Flares: Flare Head Design and Gas Composition EPA-600 /2-85-106 September 1985 Table 1-1. Agency Information Collection Activities OMB Responses EPA ICR Number 2411.01; NSPS and NESHAP for Petroleum Refineries Sector Residual Risk and Technology; OMB Number 2060-0657.1.2 This standard involves combustible gases. It is not the purpose of this standard to address the safety concerns, if any, associated with their use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.