Formerly under the jurisdiction of Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants, this test method was withdrawn in July 2022. This standard is being balloted for withdrawal with no replacement because D7576 was originally approved with a temporary precision in 2010. In 2016 after an ILS was conducted it was updated with a precision; however, the precision obtained did not have sufficient degrees of freedom for benzene and total aromatics. Since 2016, several attempts have been made to expand the ILS to attain the degrees of freedom needed (30). However, sufficient laboratories could not be obtained. It was recently re-balloted asking for an additional five years to complete it but a negative was received because the test method was extended once and in total it has been approximately 11 years since first approved. Therefore, this ballot is being balloted for withdrawal with no replacement. The test method is a regulatory requirement in California and current version will be retained by the regulatory agency but not ASTM.

5.1 Regulations in some jurisdictions, such as California, limit the concentration of benzene and total aromatic content of denatured fuel ethanol in order to reduce the ozone reactivity and toxicity of automotive evaporative and exhaust emissions. Results from this test method may be used to assess product quality and to meet new fuel regulations.

1.1 This test method covers the determination of benzene and total aromatics in finished denatured fuel ethanol by gas chromatography.

1.2 Total aromatics are determined by adding the concentrations of benzene, toluene, ethylbenzene, o-xylene, m-xylene, p-xylene, and C₉ and heavier aromatics.

1.3 The aromatic hydrocarbons are separated without interferences from other hydrocarbons in denatured fuel ethanol. Nonaromatic hydrocarbons having boiling point greater than that of n-dodecane can cause interferences with the determination of the C₉ and heavier aromatics. For the C₈ aromatics, p-xylene and m-xylene co-elute while ethylbenzene and o-xylene are separated. The C₉ and heavier aromatics are determined as a single group.

1.4 This test method covers the following concentration ranges: benzene, 0.01 % to 0.08 % by mass and total aromatics, 0.29 % to 2.67 % by mass.

1.5 Results are reported to the nearest 0.01 % by mass or liquid volume.

1.6 The values stated in SI units are to be regarded as standard.

1.6.1 Exception—The values given in parentheses are provided for information only; they may not be exact equivalents.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.