5.1 The HAFM test method is one of several available passive neutron dosimetry techniques (see, for example, Methods E854 and E1005). This test method can be used in combination with other dosimetry methods, or, if sufficient data are available from different HAFM sensor materials, as an alternative dosimetry test method. The HAFM method yields a direct measurement of total helium production in an irradiated sample. Absolute neutron fluence can then be inferred from this, assuming the appropriate spectrum integrated total helium production cross section. Alternatively, a calibration of the composite neutron detection efficiency for the HAFM method may be obtained by exposure in a benchmark neutron field where the fluence and spectrum averaged cross section are both known (see Matrix E706 IIE).
5.2 HAFMs have the advantage of producing an end product, helium, which is stable, making the HAFM method very attractive for both short-term and long-term fluence measurements without requiring time-dependent corrections for decay. HAFMs are therefore ideal passive, time-integrating fluence monitors. Additionally, the burnout of the daughter product, helium, is negligible.
5.2.1 Many of the HAFM materials can be irradiated in the form of unencapsulated wire segments (see 1.1.2). These segments can easily be fabricated by cutting from a standard inventoried material lot. The advantage is that encapsulation, with its associated costs, is not necessary. In several cases, unencapsulated wires such as Fe, Ni, Al/Co, and Cu, which are already included in the standard radiometric (RM) dosimetry sets (Table 1) can be used for both radiometric and helium accumulation dosimetry. After radiometric counting, the samples are later vaporized for helium measurement.
TABLE 1 Neutron Characteristics of Candidate HAFM Materials for Reactor Vessel SurveillanceHAFM Sensor Material
Principal Helium Producing Reaction
Thermal Neutron Cross Section, (b)
Fission Neutron Spectrum
Cross Section, (mb)A
90 % Response
Range, (MeV)A
Li
6Li(n,α)T
942
457
0.167–5.66
Be
9Be(n,α)6He ;ra 6Li
...
284
2.5–7.3
B
10B(n,α)7Li
3838
494
0.066–5.25
N
14N(n,α)11B
...
86.2
1.7–5.7
F
19F(n,α)16N
...
27.6
3.7–9.7
AlB
27Al(n,α)24Na
...
0.903
6.47–11.9
S
32S(n,α)29Si
...
...
...
Cl
35Cl(n,α)32P
...
∼13 (Cl)
2.6–8.3
TiB
47Ti(n,α)44Ca
...
0.634 (Ti)
6.5–12.8
FeB
56Fe(n,α)53Cr
...
0.395 (Fe)
5.2–11.9
NiB
58Ni(n,α)55Fe
...
5.58 (Ni)
3.9–10.1
CuB
63Cu(n,α)60Co
...
0.330
4.74–11.1
Helium Production Largely
from 56Fe and 58Ni
A Evaluated 235U fission neutron spectrum averaged helium production cross section and energy range in which 90 % of the reactions occur. All values are obtained from ENDF/B-V Gas Production Dosimetry File data. Bracketed terms indicate cross section is for naturally occurring element.B Often included in dosimetry sets as a radiometric monitor, either as a pure element foil or wire or, in the case of aluminum, as an allaying material for other elements.
5.3 The HAFM method is complementary to RM and solid state track recorder (SSTR) foils, and has been used as an integral part of the multiple foil method. The HAFM method follows essentially the same principle as the RM foil technique, which has been used successfully for accurate neutron dosimetry for the past 20 to 25 years. Various HAFM sensor materials exist which have significantly different neutron energy sensitivities from each other. HAFMs containing 10B and 6Li have been used routinely in LMFBR applications in conjunction with RM foils. The resulting data are entirely compatible with existing adjustment methods for radiometric foil neutron dosimetry (refer to Method E944).
5.4 An application for the HAFM method lies in the direct analysis of pressure vessel wall scrapings or Charpy block surveillance samples. Measurements of the helium production in these materials can provide in situ integral information on the neutron fluence spectrum. This application can provide dosimetry information at critical positions where conventional dosimeter placement is difficult if not impossible. Analyses must first be conducted to determine the boron, lithium, and other component concentrations, and their homogeneities, so that their possible contributions to the total helium production can be determined. Boron (and lithium) can be determined by converting a fraction of the boron to helium with a known thermal neutron exposure. Measurements of the helium in the material before and after the exposure will enable a determination of the boron content (7). Boron level down to less than 1 wt. ppm can be obtained in this manner.
5.5 By careful selection of the appropriate HAFM sensor material and its mass, helium concentrations ranging from ∼10−14 to 10−1 atom fraction can be generated and measured. In terms of fluence, this represents a range of roughly 1012 to 1027 n/cm2. Fluence (>1 MeV) values that may be encountered during routine surveillance testing are expected to range from ∼3 × 1014 to 2 × 10 20 n/cm2, which is well within the range of the HAFM technique.
5.6 The analysis of HAFMs requires an absolute determination of the helium content. The analysis system specified in this test method incorporates a specialized mass spectrometer in conjunction with an accurately calibrated helium spiking system. Helium determination is by isotope dilution with subsequent isotope ratio measurement. The fact that the helium is stable makes the monitors permanent with the helium analysis able to be conducted at a later time, often without the inconvenience in handling caused by induced radioactivity. Such systems for analysis exist, and additional analysis facilities could be reproduced, should that be required. In this respect, therefore, the analytical requirements are similar to other ASTM test methods (compare with Test Method E244).
Область применения1.1 This test method describes the concept and use of helium accumulation for neutron fluence dosimetry for reactor vessel surveillance. Although this test method is directed toward applications in vessel surveillance, the concepts and techniques are equally applicable to the general field of neutron dosimetry. The various applications of this test method for reactor vessel surveillance are as follows:
1.1.1 Helium accumulation fluence monitor (HAFM) capsules,
1.1.2 Unencapsulated, or cadmium or gadolinium covered, radiometric monitors (RM) and HAFM wires for helium analysis,
1.1.3 Charpy test block samples for helium accumulation, and
1.1.4 Reactor vessel (RV) wall samples for helium accumulation.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.